Potassium Iodide

Synonyms: ...,

CAS Number: 7681-11-0,

Molecular Weight: 166,

Chemical Formula: KI,

EINECS EC Number: ...,

FEMA: ...

Potassium iodide is an inorganic compound with the chemical formula KI. This white salt is the most commercially significant iodide compound.

Specifications of Potassium Iodide Commercial Pure

Appearance: White Powder
Assay: 99.0% min KI
Insoluble Matter: 0.005% max
Loss on drying: 0.2%  max at 150C
pH of 5% solution: 6.0 TO 9.2 at 25C
Chlorides & Bromides: 0.01% as Cl
Iodate (IO3): 3 ppm max
Phosphate (PO4): 0.001% max
Sulfate (SO4): 0.005% max
Barium (Ba): 0.002% max
Heavy Metals (Pb): 5 PPM max
Iron (Fe): 3 PPM max
Calcium (Ca): 0.002% max
Magnesium (Mg): 0.001% max
Sodium (Na): 0.005% max

Potassium Iodide USP

KI -- 166.00
Potassium iodide -- [7681-11-0]

Potassium Iodide contains not less than 99.0 percent and not more than 101.5 percent of KI, calculated on the dried basis.

Identification— A solution of it meets the requirements of the tests for Potassium and for Iodide.
Alkalinity— Dissolve 1.0 g in 10 mL of water, and add 0.1 mL of 0.1 N sulfuric acid and 1 drop of PhPh TS: no color is produced.
Loss on drying— Dry it at 105C for 4 hours: it loses not more than 1.0% of its weight.
Iodate— Dissolve 1.1 g in sufficient ammonia- and carbon dioxide-free water to obtain 10 mL of solution, and transfer to a color-comparison tube. Add 1 mL of starch TS and 0.25 mL of 1.0 N sulfuric acid, mix, and compare the color with that of a control containing, in a similar volume, 100 mg of Potassium Iodide, 1 mL of standard iodate solution [prepare by diluting 1 mL of potassium iodate solution (1 in 2500) with water to 100 mL], 1 mL of starch TS, and 0.25 mL of 1.0 N sulfuric acid. Any color produced in the solution of the test specimen does not exceed that in the control: not more than 4 µg per g is found.
Limit of nitrate, nitrite, and ammonia— To a solution of 1 g in 5 mL of water contained in a test tube of about 40-mL capacity add 5 mL of 1 N sodium hydroxide and about 200 mg of aluminum wire. Insert a pledget of purified cotton in the upper portion of the test tube, and place a piece of moistened red litmus paper over the mouth of the tube. Heat the test tube and its contents in a steam bath for 15 minutes: no blue coloration of the paper is discernible.
Thiosulfate and barium— Dissolve 0.5 g in 10 mL of ammonia- and carbon dioxide-free water, and add 2 drops of 2 N sulfuric acid: no turbidity develops within 1 minute.
Heavy metals— Dissolve 2.0 g in 25 mL of water: the limit is 0.001%.
Assay— Dissolve about 500 mg of Potassium Iodide, accurately weighed, in about 10 mL of water, and add 35 mL of hydrochloric acid. Titrate with 0.05 M potassium iodate VS until the dark brown solution which is produced becomes pale brown. Add 2 to 3 drops of amaranth TS, and continue the titration slowly until the red color just changes to yellow. Each mL of 0.05 M potassium iodate is equivalent to 16.60 mg of KI.

Potassium Iodide BP (Ph Eur monograph 0186)

KI -- 166.0 -- 7681-11-0

Content: 99.0 per cent to 100.5 per cent (dried substance).

CHARACTERS
Appearance: White or almost white powder or colourless crystals.
Solubility: Very soluble in water, freely soluble in glycerol, soluble in ethanol (96 per cent).

IDENTIFICATION
A. Solution S (see Tests) gives the reactions of iodides (2.3.1).
B. Solution S gives the reactions of potassium (2.3.1).

TESTS
Solution S: Dissolve 10.0 g in carbon dioxide-free water R prepared from distilled water R and dilute to 100 ml with the same solvent.
Appearance of solution: Solution S is clear and colourless.
Alkalinity: To 12.5 ml of solution S add 0.1 ml of bromothymol blue solution R1. Not more than 0.5 ml of 0.01 M hydrochloric acid is required to change the colour of the indicator.
Iodates
: To 10 ml of solution S add 0.25 ml of iodide-free starch solution R and 0.2 ml of dilute sulphuric acid R and allow to stand protected from light for 2 min. No blue colour develops.
Sulphates: Maximum 150 ppm.
Dilute 10 ml of solution S to 15 ml with distilled water R.
Thiosulphates
: To 10 ml of solution S add 0.1 ml of starch solution R and 0.1 ml of 0.005 M iodine. A blue colour is produced.
Iron: Maximum 20 ppm.
Dilute 5 ml of solution S to 10 ml with water R.
Heavy metals
: Maximum 10 ppm.
12 ml of solution S complies with test A. Prepare the reference solution using lead standard solution (1 ppm Pb) R.
Loss on drying: Maximum 1.0 per cent, determined on 1.00 g of previously powdered substance by drying in an oven at 105C for 3 h.

POTASSIUM IODIDE IP

KI -- Mol. Wt. 166.00

Category: Antithyroid; antifungal; expectorant.
Description: Colourless crystals or white powder; odourless
Solubility: Very soluble in water; freely soluble in glycerin; soluble in ethanol (95%).

STANDARDS
Potassium Iodide contains not less than 99.0 per cent and not more than 100.5 per cent of KI, calculated with reference to the dried substance.
Identification: A 10% w/v solution in carbon dioxide-free water (solution A) gives the reactions of potassium salts and of iodides.
Alkalinity: To 10 ml of solution A add 0.2 ml of 0.01M sulphuric acid; no colour is produced on addition of a drop of PhPh solution. .
Clarity and colour of solution: Solution A is clear and colourless.
Arsenic: Dissolve 5.0 g in 50 ml of 'water and 12 ml of stannated hydrochloric acid AsT. The resulting solution complies with the limit test for arsenic (2 ppm).
Heavy metals: Not more than 10 ppm, determined on 2.0 g
Iron: Solution A complies with the limit lest for iron (20 ppm).
Barium: Dissolve 0.5 g in 10 ml of water and add 1 ml of dilute sulphuric acid; no turbidity develops within one minute.

>Potassium Iodide FCC Food Grade

KI Formula wt 166.00
CAS: [7681-11-0]

DESCRIPTION
Potassium Iodide occurs as hexahedral crystals, either transparent and colorless or somewhat opaque and white, or as a white, granular powder. It is stable in dry air but slightly hygroscopic in moist air. One gram is soluble in 0.7 mL of water at 25°, in 0.5 mL of boiling water, in 2 mL of glycerin, and in 22 mL of alcohol.

REQUIREMENTS
Identification:
A. A 1:10 aqueous solution responds to the tests for Potassium and for Iodide.
B. The pH of a 1:20 aqueous solution is between 6 and 10.
Assay: Not less than 99.0% and not more than 101.5% of KI after drying.
Iodate: Not more than 4 mg/kg.
Lead: Not more than 4 mg/kg.
Loss on Drying: Not more than 1%.
Nitrate, Nitrite, and Ammonia: Passes test.
Thiosulfate and Barium: Passes test.

Potassium Iodide Analytical Reagent Grade Chemical

KI -- Formula Weight 166.00
CAS Number 7681-11-0

REQUIREMENTS
Assay: Minimum 99.0% KI
pH of a 5% solution: 6.0-9.2 at 25C

MAXIMUM ALLOWABLE
Insoluble matter: 0.005%
Loss on drying at 150C: 0.2%
Chloride and bromide (as Cl): 0.01%
Iodate (IO3): 3 ppm
Nitrogen compounds (as N): 0.001%
Phosphate (PO4): 0.001%
Sulfate (SO4): 0.005%
Barium (Ba): 0.002%
Heavy metals (as Pb): 5 ppm
Iron (Fe): 3 ppm
Calcium (Ca): 0.002%
Magnesium (Mg): 0.001%
Sodium (Na): 0.005%

Potassium iodide is a precursor to silver iodide (AgI) an important chemical in photography. KI is a component in some disinfectants and hair treatment chemicals. KI is also used as a fluorescence quenching agent in biomedical research.

The major uses of KI include use as a nutritional supplement in animal feeds and also the human diet. It is the most common additive used to "iodize" table salt, a public health measure to prevent iodine deficiency in populations which get little seafood. The oxidation of iodide causes slow loss of iodine content from iodized salts that are exposed to excess air. Potassium iodide is also used in several pharmaceutical preparations and for protection against nuclear radiation.